Reid Vapor Pressure and Drum Preserve explanation by Jim of Dyno Tech Research
Using compressed nitrogen gas to properly store and
dispense drummed racing gasoline and other liquids.
Failure to properly store
racing gasoline can result in the loss of the gasoline’s “front ends”. This can
result in a subsequent lean condition in the engine’s combustion chambers
leading to reduced HP, and possibly detonation and preignition in otherwise
properly tuned engines! Racing gasoline should be stored in sealed and
pressurized containers to preserve the critical front ends of the fuel!
Racing gasoline is not a pure
substance as are water and methanol, but is a mixture of hundreds of petroleum
hydrocarbon molecules. Those petroleum hydrocarbon molecules each have precise
boiling points—from approximately 50 degrees F to 400 degrees F. The molecules
that have the lowest boiling temperatures are referred to as the gasoline’s
“front ends”. These important front end components are the first part of the
gasoline to begin vaporizing in an engine’s cool intake tract, and are critical
in creating optimal vaporization especially at low operating temperatures. And,
being the first to vaporize, the front ends are the first to ignite and create
the heat necessary to quickly vaporize the heavier molecules, which will then
be able to burn in the combustion chambers. Front
ends are also the first to boil off and “escape” into the atmosphere from
racing gasoline improperly stored at room temperature (or higher) in
unpressurized containers.
But how can those important
front ends escape from resealed drums? We used to think that replacing the
threaded cap back tightly in the bung in our drum of racing gasoline was an
adequate means of keeping the remainder of the stored race gas “fresh”. How
wrong we were! Racing gasoline stored in sealed containers (drums or jugs) acts
very much like carbonated Cola stored in two liter plastic bottles. Every time
the Cola bottle is opened to pour off a glassful of beverage to consume, some
carbonation (CO2) is released to the atmosphere as a “whoosh”. Then when the
bottle is resealed, more of the CO2 boils off to rebuild pressure in the
growing headspace in the bottle. A full bottle of Cola has very little
headspace to fill with pressurized CO2 gas, but as the contents are consumed,
that headspace volume increases, requiring ever more dissolved CO2 to be
released to rebuild the pressure. And each time the pressure is released from
the bottle, the CO2 remaining in the stored Cola is reduced as a % of what it
originally had. Eventually, the remaining Cola’s carbonation is diminished to
the point of being unpleasant. It’s now “flat”, or “dead” like stored racing
gasoline that’s been subjected to similar abuse.
When you first open your
“sealed” 50 gallon drum of racing gasoline, you are rewarded with a pleasant,
fragrant “woosh” of boiled-off “front ends” escaping into the atmosphere from
the tiny headspace in the full drum, above the gasoline, very slightly reducing
the gasoline’s actual RVP (Reid Vapor Pressure = the head pressure created by
the front ends that boil off from the gasoline in a sealed container at 100 F).
But all is good—the first ten gallons you siphoned out of the drum is dandily
fresh and loaded with most of the front end molecules that were blended into
the gasoline at the refinery. Your engine is happy, making maximum horsepower
at the 13/1 ratio of air to fuel (measured by weight) you tuned it to, most of
which vaporizes and burns in the combustion chamber. But now the headspace in
the drum above the stored racing gasoline has grown by the air volume left by
the 10 gallons of siphoned-off racing gasoline. Now, lots more light ends can
boil off to rebuild the pressure in the resealed drum, further reducing the
actual RVP of the 40 gallons left in the drum. Then next time we crack open the
drum to siphon out more racing gasoline, the “whoosh” releases even more light
end gases into the atmosphere, further reducing the RVP of what’s left. Now
headspace is even greater, and the loss of light ends is multiplied each time
the drum is opened and resealed. Besides the loss of critical front ends, the
siphoned off fuel is replaced with air containing various amounts of water that
can combine with the remaining race gasoline! By the time we’re down to the
last 10 or 20 gallons in the “sealed” drum, the light ends are essentially gone,
and the race gasoline left is STALE and even perhaps contaminated with water!
Now, the engine that’s been tuned perfectly with fresh fuel at 13/1 A/F now may
be having perhaps only 80% of the stale fuel vaporizing in the combustion
chambers and the remaining 20% vaporizing and burning in the hot exhaust
system! So that 13/1 is now burning at an actual 16/1—still firing cleanly (the
explosive limit of air/gasoline ranges from 10/1 to 17/1) but way too lean for
max HP, and creating much higher combustion chamber temperatures that can
create detonation and preignition and/ or piston seizures! But the EGT’s are
low—how can that be? All the fuel that finally vaporizes on the way out of the
combustion chamber just cools the exhaust temperature probes, then may finally
burn as it combines with the unused oxygen in the exhaust system! And, your
wideband A/F ratio meter’s O2 sensor in the exhaust pipe still shows 13/1.
You’re being fooled by stale race gasoline as your engine suffers from at best,
reduced HP and at worst, seized piston(s)!
What to do?
The most practical means to
safely store and dispense racing gasoline is to pressurize the drum with just
enough nitrogen gas to prevent the front ends of the gasoline from evaporating
at the actual stored temperature of the gasoline. If a particular blend of
racing gasoline has a published RVP rating (100 degrees F) of, say, 6 psi then
it should be pressurized to approximately 3 psi (@half of RVP) at typical 70
degrees F storage. Then, the 3 psi nitrogen gas pressure can be used to
dispense gasoline as needed from a valved siphon hose from the bung to the
bottom of the drum. The displaced fuel is replaced with inert, dry nitrogen gas
eliminating any possibility of water contamination! It only takes a few dollars
worth of nitrogen gas to preserve and dispense 50 gallons of racing gasoline.
Carbon steel racing gasoline
storage drums are typically hydrostatically tested—50 gallon size to 36.8 psi
and 30 gallon size to 44.1 psi.
The Drum Preserve system uses
a specially manufactured low-pressure solid brass nitrogen regulator that is
designed to deliver maximum nitrogen pressure well below the drums’ hydrostatic
test pressure. And, each billet aluminum Drum-Storage bung has a 10 psi
pressure relief valve to help provide protection against accidental
over-pressurization of the drum.